Nano Phosphate is a type of Lithium chemistry that is regarded as the best type on the market. So yes you could go and buy a competitors lithium tool/battery, but their lithium won't last compared to Dewalt's Nano Phosphate XRP battteries. I believe this is the kit you are looking for:
http://www.amazon.com/DEWALT-DCK275L-18-Volt-Lithium-Ion-Impact/dp/B001UHOUVCIt has the Nano Phosphate Lithium Batteries and the newer DCD950/970 Hammerdrill, with the same DC825/827 Impact Driver.
To answer your question about the DCK440X, it comes with NiCad Batteries (same as in the DCK245X
Lithium is the "newer technology" but NiCad isn't something Dewalt will be going away from any time soon. It is way more affordable to their customers, you can find 2 XRP NiCad batteries for $99-$119 at the big boxes where 1 XRP Lithium (or Nano) battery usually retails for around $130. Both are good batteries.